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• W2013093428 abstract "Thermodynamic (potentiometric and calorimetric) and spectroscopic (1H NMR, 119Sn Mössbauer) studies were performed in aqueous solution in order to characterize the interaction of dimethyltin(IV) cation with citrate ligand. Six species {(CH3)2Sn(cit)−; [(CH3)2Sn]2(cit)22−; (CH3)2Sn(cit)H0; (CH3)2Sn(cit)OH2−; [(CH3)2Sn]2(cit)OH0; [(CH3)2Sn]2(cit)(OH)2−} were found. All the species formed in this system are quite stable and formation percentages are fairly high. For example, at pH = 7.5 and C = Ccit = 10 mmol l−1, Σ% for [(CH3)2Sn]2(cit)(OH)2− and (CH3)2Sn(cit)OH2− species reaches 65%. Overall thermodynamic parameters obtained show that the main contribution to stability is entropic in nature. Thermodynamic parameters were discussed in comparison with a simple tricarboxylate ligand (1,2,3-propanetricarboxylate). Two empirical relationships were derived from thermodynamic formation parameters. Spectroscopic results fully confirm the speciation model defined potentiometrically and show the mononuclear species to have an eq-(CH3)2Tbp structure with different arrangements around the metal, while for [(CH3)2Sn]2(cit)(OH)2− there are two different Sn(IV) environments, namely trans-(CH3)2 octahedral and cis-(CH3)2 Tbp. Copyright © 2005 John Wiley & Sons, Ltd." @default.
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• W2013093428 date "2006-01-01" @default.
• W2013093428 modified "2023-10-16" @default.
• W2013093428 title "Thermodynamic and spectroscopic study of the binding of dimethyltin(IV) by citrate at 25 °C" @default.
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• W2013093428 doi "https://doi.org/10.1002/aoc.1076" @default.
• W2013093428 hasPublicationYear "2006" @default.
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