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- W2013093864 abstract "Abstract The investigation and characterization of FeCl3-graphite 37 years ago by Rudorff and Schulz opened a new field in the chemistry of graphite which has aroused widespread and continuing interest. We will trace the development of this field, emphasising the preparative aspects, the compositions, the connection between the crystal structures of the metal halides and the distance of the carbon planes separated by intercalated metal halide, and the reactions of the inserted metal halides. By contrast to the extensive studies of the intercalation of metal halides, the reactions of graphite with metal bromides have received scant attention. Recently we have prepared some new graphite-metal bromide compounds. The results of these investigations will be presented and discussed. Comparisons will be made between graphite-metal chloride and −bromide compounds. We also present some more recent results concerning the intercalation of the trichlorides of the rare earths currently being investigated in our laboratory. We have found that gaseous complexes may provide a useful method for the preparation of certain graphite-metal halide compounds. Spectral data obtained for graphite-metal halide compounds by reflectance spectroscopy will be presented." @default.
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- W2013093864 date "1977-12-01" @default.
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- W2013093864 title "The intercalation of metal chlorides and bromides into graphite" @default.
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- W2013093864 doi "https://doi.org/10.1016/0025-5416(77)90011-8" @default.
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