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- W2013112979 abstract "The b1Σ+(b0+) → X3Σ−(X10+, X21) and a1Δ(a2) → X3Σ−(X10+, X21) transitions of group VI—group VI and group V—group VII diatomic molecules in the near-IR spectral region were investigated by chemiluminescence measurements, excimer laser pulse photolysis and dye laser fluorescence. Spectroscopic identification of the b → X transitions of S2, SeS and Se2 and of the a1Δ,v′ = 0 → X3Σ−,v″ = 0 band of SO was achieved by comparing medium resolution Fourier transform IR spectra of the O2(a1Δg)-sensitized chemiluminescence of these molecules with computer-simulated band shapes. Improved data for the electronic state energies of these molecules were obtained. Time-resolved studies of the b → X emissions of SO, SeO, NI, PCl, PBr, SbF, SbCl and SbBr following excimer laser pulse photolysis of suitable parent compounds or pulsed dye laser excitation of the radicals in discharge flow systems are reported. From these studies preliminary data for the radiative lifetimes of the b states and quenching rate constants were deduced. The energy exchange and energy pooling processes operative in the O2(a1Δg)-sensitized chemiluminescence systems and possible population inversions between the vibronic states are discussed." @default.
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- W2013112979 date "1984-06-01" @default.
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- W2013112979 title "O2(a1Δg)-sensitized chemiluminescence of a1Δ → X3Σ− and b1Σ+ → X3Σ− transitions of group VI—group VI and group V—group VII diatomic molecules" @default.
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- W2013112979 doi "https://doi.org/10.1016/0047-2670(84)87043-4" @default.
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