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• W2013114316 abstract "Nitrogen heterocycles can be prepared by performing ring-expansion reactions of gamma-silyloxy-gamma-lactams, which are available by the annulation reactions of allylic silanes. Nucleophilic substitution of the annulation products and subsequent translactamization of nitrogen-tethered gamma-lactams provide six-, seven-, and eight-membered ring lactams. An enantiomerically enriched delta-lactam formed from this method was elaborated to form the hydroxypiperidine core structure of the pseudodistomin alkaloids." @default.
• W2013114316 created "2016-06-24" @default.
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• W2013114316 date "2009-08-13" @default.
• W2013114316 modified "2023-09-25" @default.
• W2013114316 title "Formation of Medium-Sized Nitrogen Heterocycles from γ-Silyloxy-γ-Lactams" @default.
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• W2013114316 doi "https://doi.org/10.1021/jo900869k" @default.
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