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• W2013115548 abstract "Configurational-bias Monte Carlo simulations in the grand canonical ensemble with histogram reweighting were used to obtain the vapor-liquid coexistence curves of three hexane isomers physisorbed on a flat gold substrate. Examination of the critical ordering operator distributions confirms that these systems exhibit critical behavior consistent with the 2D Ising universality class. The critical temperatures for 2,2-dimethylbutane, 2,3-dimethylbutane, and n-hexane were determined as T(2D)(c) = 195.0, 161.2, and 152.4 K, respectively. This is qualitatively different from the behavior observed for bulk (3D) fluids, where branched alkanes typically exhibit lower critical temperatures than their linear counterparts." @default.
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• W2013115548 date "2000-10-16" @default.
• W2013115548 modified "2023-10-14" @default.
• W2013115548 title "Effect of Branching on the Fluid Phase Behavior of Alkane Monolayers" @default.
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• W2013115548 doi "https://doi.org/10.1103/physrevlett.85.3460" @default.
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