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- W2013115783 abstract "The chemistry of the bisalkyne molybdenum complexes [Mo(L)(η2-RC2R)2)η-C5H5 or η5-C9H7)][BF4] (L = CO or MeCN) is described. The reaction of the carbonyl cation with o-diphenylphosphinostyrene affords an alkyne-alkene complex which is transformed into a 1,3-diene complex in refluxing MeCN via CC bond formation and a 1,3-H shift, whereas the acetonitrile species with cyclo-octatetraene and cyclo-heptatriene undergo (6 + 2)π addition reactions with the co-ordinated alkyne. Addition of one electron to the acetonitrile cation leads to novel alkyne-linking reactions at two molybdenum centres." @default.
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- W2013115783 date "1986-01-01" @default.
- W2013115783 modified "2023-09-26" @default.
- W2013115783 title "Molybdenum-centred carboncarbon bond formation reactions" @default.
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- W2013115783 doi "https://doi.org/10.1016/s0277-5387(00)84945-1" @default.
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