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- W2013117589 abstract "Poly(quarterthiophene-alt-benzothiadiazole), PQT12oBT and PQT12BT, were synthesized through the Stille coupling reaction. The UV–visible absorption spectrum of PQT12oBT showed peaks at 535 nm; moreover, it exhibited a higher molar absorption coefficient (ε=44,000 M−1 cm−1 at 535 nm) than PQT12BT (3300 M−1 cm−1) in chloroform solution. The optical band gap of PQT12oBT was calculated 1.74 eV in solid state. The HOMO and LUMO energy levels of PQT12oBT were −5.18 and −3.44 eV, respectively. From the results of X-ray diffraction measurements, the lamellar d-spacing of PQT12oBT in out-of-plane direction was determined to be 21.6 Å, and the π–π stacking distance between layers was found to be 4.09 Å, with a slight edge-on orientation. Bulk heterojunction-type polymer solar cells were fabricated. With a 1:1 ratio of PQT12oBT and PC71BM, the values of open circuit voltage (Voc), short circuit current density (Jsc), fill factor (FF), and power conversion efficiency (PCE) were found to be 0.77 V, 8.9 mA cm−1, 62.4%, and 4.2%, respectively. In addition, PCE was increased up to 4.4% by the addition of 1-bromonaphthalene (1-BrNT) to the active layer." @default.
- W2013117589 created "2016-06-24" @default.
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- W2013117589 date "2014-01-01" @default.
- W2013117589 modified "2023-09-23" @default.
- W2013117589 title "Effect of replacing proton with alkoxy side chain for donor acceptor type organic photovoltaics" @default.
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- W2013117589 doi "https://doi.org/10.1016/j.solmat.2013.09.023" @default.
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