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- W2013118300 abstract "Reaction of [W{C(OLi)NiPr2}(CO)5] with X2PPh3 and PPh3 gives the aminomethylidyne complexes mer- [W(CNiPr2)X(CO)3(PPh3)] (X Cl, Br) in a convenient one-pot procedure from [W(CO)6]. The route appears to be general, providing ready access to a range of alkylidyne complexes including [W(C-naphthyl)Cl(CO)2(tmeda)], [W(C-thienyl)Cl(CO)2(tmeda)], [W(C-naphthyl)Cl(CO)3(PPh3)] [W(C-thienyl)Cl(CO)3(PPh3)] and [W(CNiPr2Cl(CO)2(2,2′-bipyridyl)]" @default.
- W2013118300 created "2016-06-24" @default.
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- W2013118300 date "1993-12-01" @default.
- W2013118300 modified "2023-09-28" @default.
- W2013118300 title "Phosphine dihalides as reagents for synthesis of tungsten aminomethylidyne complexes" @default.
- W2013118300 cites W1193644091 @default.
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- W2013118300 doi "https://doi.org/10.1016/0022-328x(93)83428-x" @default.
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