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• W2013118853 abstract "This study investigated the sorption kinetics of a model solute (naphthalene) with a series of biochars prepared from a pine wood at 150-700 °C (referred as PW100-PW700) to probe the effect of the degree of carbonization of a biochar. The samples were characterized by the elemental compositions, thermal gravimetric analyses, Fourier transform IR spectroscopy, scanning electron microscopy, Brunauer-Emmett-Teller-N(2) surface areas (SA), and pore size distributions. Naphthalene exhibited a fast rate of sorption to PW150 owning a high oxygen content and a small SA, due supposedly to the solute partition into a swollen well-hydrated uncarbonized organic matter of PW150. The partial removal of polar-group contents in PW250/PW350, which increased the compactness of the partition medium, decreased the diffusion of the solute into the partition phase to result in a slow sorption rate. With PW500 and PW700 displaying low oxygen contents and high SA, the solute sorption rates were fast, attributed to the near exhaustion of a partition phase in the sample and to the fast solute adsorption on the carbonized biochar component. The results illustrate that the sorption rate of a solute with biochars is controlled largely by the solute's diffusivity in the biochar's partition phase, in which the medium compactness affects directly the solute diffusivity." @default.
• W2013118853 created "2016-06-24" @default.
• W2013118853 creator A5027235329 @default.
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• W2013118853 date "2012-09-26" @default.
• W2013118853 modified "2023-10-14" @default.
• W2013118853 title "Fast and Slow Rates of Naphthalene Sorption to Biochars Produced at Different Temperatures" @default.
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• W2013118853 doi "https://doi.org/10.1021/es302345e" @default.
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