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• W2013128305 abstract "On the basis of the assignments of the methylene wagging bands described in the preceding paper (Part 1), FT-IR studies have been applied to the β‘1-form of 1,2-dipalmitoyl-3-myristoyl-sn-glycrerol (PPM). PPM has the most stable form of β‘-type, in contrast to ordinary triacylglycerols, which have the most stable form of β-type. The degrees of inclination of the acyl chains with respect to the lamellar interface were determined by two FT-IR techniques of attenuated total reflection and oblique transmission. The acyl chains were packed in orthorhombic perpendicular (O⊥) subcell as revealed in the absorption spectra of polymethylene scissoring and rocking modes. As for the acyl chain conformation, it was found that a palmitoyl chain and a myristoyl chain extend to form an all-trans conformation, while the second palmitoyl chain takes a bent conformation in the neighborhood of the ester bond. The acyl chain axis tilts against both the as- and the bs-axis of the O⊥ subcell, yet the degree of inclination against the bs-axis is slightly larger than that against the as-axis. The as-axis is inclined unidirectionally, while the bs-axis is alternately inclined along the successive layer." @default.
• W2013128305 created "2016-06-24" @default.
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• W2013128305 date "1997-10-01" @default.
• W2013128305 modified "2023-09-27" @default.
• W2013128305 title "Structural Analyses and Triacylglycerol Polymorphs with FT-IR Techniques. 2. β‘₁-Form of 1,2-Dipalmitoyl-3-myristoyl-<i>sn</i>-glycerol" @default.
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• W2013128305 doi "https://doi.org/10.1021/jp971305b" @default.
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