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- W2013130854 abstract "This paper reports on the decisive effect that solvent has on the atom transfer radical polymerization of methyl methacrylate (MMA) at low temperature. In butanone and in the presence of a copper(I)/bipyridine complex, the polymerization is controlled and the molecular weight distribution is narrow, at 0°C and even lower. This control is maintained when ε-caprolactone (CL) is substituted for butanone. The use of this polymerizable solvent together with a novel dual initiator, 2-hydroxyethyl, 2′-methyl-2′-bromopropionate, is an efficient strategy to prepare PMMA-b-PCL diblock polymers in a one-pot process." @default.
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- W2013130854 date "2002-04-01" @default.
- W2013130854 modified "2023-10-09" @default.
- W2013130854 title "The Use of e-Caprolactone as a Polymerizable Solvent for the Atom Transfer Radical Polymerization of MMA at Low Temperature" @default.
- W2013130854 doi "https://doi.org/10.1002/1521-3935(20020401)203:7<968::aid-macp968>3.0.co;2-x" @default.
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