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- W2013131438 abstract "Abstract Chitosan is well known for its binding properties toward transition metal ions. We prepared a chemical hydrogel based on chitosan using as cross-linking agent a polyfunctionalized β-cyclodextrin and studied the structural and catalytic features of this hydrogel loaded with copper(II) ions in aqueous medium. Stability of the complex and its structural characteristics were determined by isothermal microcalorimetry and EPR spectroscopy, respectively. Kinetics of the oxidation of ( d , l )-adrenaline and of l -adrenaline catalyzed by copper (II) bound to the matrix was monitored with a Clark-type O-2 sensitive electrode. The advantages of working with a heterogeneous system are coupled with the preservation of both structural and catalytic features of copper(II) site in the matrix with respect to copper(II) ions bound to chitosan derivatives in solution." @default.
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- W2013131438 date "1998-04-01" @default.
- W2013131438 modified "2023-10-14" @default.
- W2013131438 title "Networks based on chitosan and oxidized cyclodextrin—II. Structural and catalytic features of a copper (II)-loaded network" @default.
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- W2013131438 doi "https://doi.org/10.1016/s0966-7822(97)00026-9" @default.
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