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- W2013132029 abstract "Silicide coatings were formed on two austenitic heat-resistant steels by chemical vapour deposition at high temperatures from flowing H2silane mixtures. Coatings produced using tetrachlorosilane were grown to thicknesses of up to 60 μm and contained nickel silicides, (Cr, Ni) silicides and iron silicides. These coatings were porous near the coating-alloy interface and were prone to separation when subject to temperature cycling. The effectiveness of these coatings in reducing carburization when subsequently exposed to H2-hydrocarbon mixtures at 1273 K was negligible. Coatings were also produced using dichlorodimethylsilane which pyrolyses to produce both silicon and carbon. The resultant coatings were of similar composition but without the porosity. These coatings also were liable to separation on temperature cycling. Examination of the substrate alloys revealed that extensive carburization had occurred during formation of the coating. Subsequent exposure tests in H2-hydrocarbon atmospheres showed that the coatings had no effect. It is concluded that silicide coatings are not very effective against carburization in non-oxidizing atmospheres." @default.
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- W2013132029 date "1987-04-01" @default.
- W2013132029 modified "2023-09-26" @default.
- W2013132029 title "Silicide coatings for carburization protection" @default.
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- W2013132029 doi "https://doi.org/10.1016/0025-5416(87)90070-x" @default.
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