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- W2013133259 abstract "A new cyclohexasilicate, K2PbSi3O9·H2O, was synthesized under mild hydrothermal conditions. The crystal structure was solved by powder X-ray diffraction data. The unit cell is monoclinic, a = 6.5623(2), b = 11.7757(3), c = 13.0483(3) Å, β = 103.57(2)°, space group P21/n, Z = 4. The structure consists of a framework of isolated Si6O18 rings with the Pb(IV) located in octahedral holes. Thus, the structural formula can be written as Pb2K4{uB, 6t}[Si6O18]·2H2O. The structure encloses one eight membered monodimensional channel running parallel to the a axis of about 3.0 × 5.5 Å2. This channel is filled with one of the two crystallographically independent potassium cations and the water molecules. A second smaller six-membered ring channel along a is also present and contains the second K+. This compound represents a monoclinic version of the better-known orthorhombic members of the family." @default.
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- W2013133259 date "2001-02-01" @default.
- W2013133259 modified "2023-10-16" @default.
- W2013133259 title "Synthesis and structural study of K2PbSi3O9·H2O with the structure of kostylevite" @default.
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- W2013133259 doi "https://doi.org/10.1016/s0025-5408(01)00532-3" @default.
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