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- W2013140073 abstract "Abstract Molecular brushes of poly(2‐oxazoline)s were prepared by living anionic polymerization of 2‐iso‐propenyl‐2‐oxazoline to form the backbone and subsequent living cationic ring‐opening polymerization of 2‐ n ‐ or 2‐ iso ‐propyl‐2‐oxazoline for pendant chain grafting. In situ kinetic studies indicate that the initiation efficiency and polymerization rates are independent from the number of initiator functions per initiator molecule. This was attributed to the high efficiency of oxazolinium salt and the stretched conformation of the backbone, which is caused by the electrostatic repulsion of the oxazolinium moieties along the macroinitiator. The resulting molecular brushes showed thermoresponsive properties, that is, having a defined cloud point (CP). The dependence of the CP as a function of backbone and side chain length as well as concentration was studied." @default.
- W2013140073 created "2016-06-24" @default.
- W2013140073 creator A5024437898 @default.
- W2013140073 creator A5025070309 @default.
- W2013140073 creator A5085402781 @default.
- W2013140073 date "2012-04-17" @default.
- W2013140073 modified "2023-10-17" @default.
- W2013140073 title "Thermoresponsive Poly(2‐oxazoline) Molecular Brushes by Living Ionic Polymerization: Kinetic Investigations of Pendant Chain Grafting and Cloud Point Modulation by Backbone and Side Chain Length Variation" @default.
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- W2013140073 doi "https://doi.org/10.1002/macp.201200015" @default.
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