Matches in SemOpenAlex for { <https://semopenalex.org/work/W2013140168> ?p ?o ?g. }
Showing items 1 to 91 of
91
with 100 items per page.
- W2013140168 endingPage "4930" @default.
- W2013140168 startingPage "4926" @default.
- W2013140168 abstract "Activation of either anomer of S-phenyl 2,3-di-O-benzyl-4,6-O-benzylidene-1-deoxy-1-thia-D-glucopyranoside with triflic anhydride in dichloromethane at -78 degrees C in the presence of 2,6-di-tert-butyl-4-methylpyridine affords a highly active glycosylating species which, on addition of alcohols, provides alpha-glucosides with high selectivity. This selectivity stands in stark contrast to the analogous mannopyranoside series, which affords the beta-mannosides with excellent selectivity under the same conditions. Low-temperature NMR experiments support the notion that a glucosyl triflate is formed in the initial activation step. Possible reasons for the diverging stereoselectivity in the gluco and manno series are discussed." @default.
- W2013140168 created "2016-06-24" @default.
- W2013140168 creator A5027175360 @default.
- W2013140168 creator A5057972673 @default.
- W2013140168 date "1999-06-01" @default.
- W2013140168 modified "2023-10-18" @default.
- W2013140168 title "Chemistry of 4,6-<i>O</i>-Benzylidene-<scp>d</scp>-glycopyranosyl Triflates: Contrasting Behavior between the Gluco and Manno Series" @default.
- W2013140168 cites W1967468522 @default.
- W2013140168 cites W1973382963 @default.
- W2013140168 cites W2007330836 @default.
- W2013140168 cites W2014353301 @default.
- W2013140168 cites W2014521318 @default.
- W2013140168 cites W2016089257 @default.
- W2013140168 cites W2025708871 @default.
- W2013140168 cites W2032056043 @default.
- W2013140168 cites W2057906588 @default.
- W2013140168 cites W2062512362 @default.
- W2013140168 cites W2071004159 @default.
- W2013140168 cites W2083294340 @default.
- W2013140168 cites W2094312809 @default.
- W2013140168 cites W2108523300 @default.
- W2013140168 cites W2128155040 @default.
- W2013140168 cites W2133857747 @default.
- W2013140168 cites W2172087043 @default.
- W2013140168 cites W2949114538 @default.
- W2013140168 cites W2951065849 @default.
- W2013140168 doi "https://doi.org/10.1021/jo990243d" @default.
- W2013140168 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/11674572" @default.
- W2013140168 hasPublicationYear "1999" @default.
- W2013140168 type Work @default.
- W2013140168 sameAs 2013140168 @default.
- W2013140168 citedByCount "138" @default.
- W2013140168 countsByYear W20131401682012 @default.
- W2013140168 countsByYear W20131401682013 @default.
- W2013140168 countsByYear W20131401682014 @default.
- W2013140168 countsByYear W20131401682015 @default.
- W2013140168 countsByYear W20131401682016 @default.
- W2013140168 countsByYear W20131401682017 @default.
- W2013140168 countsByYear W20131401682018 @default.
- W2013140168 countsByYear W20131401682019 @default.
- W2013140168 countsByYear W20131401682020 @default.
- W2013140168 countsByYear W20131401682021 @default.
- W2013140168 countsByYear W20131401682022 @default.
- W2013140168 countsByYear W20131401682023 @default.
- W2013140168 crossrefType "journal-article" @default.
- W2013140168 hasAuthorship W2013140168A5027175360 @default.
- W2013140168 hasAuthorship W2013140168A5057972673 @default.
- W2013140168 hasConcept C118792377 @default.
- W2013140168 hasConcept C155647269 @default.
- W2013140168 hasConcept C161790260 @default.
- W2013140168 hasConcept C178790620 @default.
- W2013140168 hasConcept C181647583 @default.
- W2013140168 hasConcept C185592680 @default.
- W2013140168 hasConcept C21774173 @default.
- W2013140168 hasConcept C2780400988 @default.
- W2013140168 hasConcept C2780471494 @default.
- W2013140168 hasConcept C71240020 @default.
- W2013140168 hasConcept C7947691 @default.
- W2013140168 hasConceptScore W2013140168C118792377 @default.
- W2013140168 hasConceptScore W2013140168C155647269 @default.
- W2013140168 hasConceptScore W2013140168C161790260 @default.
- W2013140168 hasConceptScore W2013140168C178790620 @default.
- W2013140168 hasConceptScore W2013140168C181647583 @default.
- W2013140168 hasConceptScore W2013140168C185592680 @default.
- W2013140168 hasConceptScore W2013140168C21774173 @default.
- W2013140168 hasConceptScore W2013140168C2780400988 @default.
- W2013140168 hasConceptScore W2013140168C2780471494 @default.
- W2013140168 hasConceptScore W2013140168C71240020 @default.
- W2013140168 hasConceptScore W2013140168C7947691 @default.
- W2013140168 hasIssue "13" @default.
- W2013140168 hasLocation W20131401681 @default.
- W2013140168 hasLocation W20131401682 @default.
- W2013140168 hasOpenAccess W2013140168 @default.
- W2013140168 hasPrimaryLocation W20131401681 @default.
- W2013140168 hasRelatedWork W1599976097 @default.
- W2013140168 hasRelatedWork W1989253866 @default.
- W2013140168 hasRelatedWork W2038061226 @default.
- W2013140168 hasRelatedWork W2067390758 @default.
- W2013140168 hasRelatedWork W2112764830 @default.
- W2013140168 hasRelatedWork W2312402448 @default.
- W2013140168 hasRelatedWork W2949822283 @default.
- W2013140168 hasRelatedWork W2951198064 @default.
- W2013140168 hasRelatedWork W2953220363 @default.
- W2013140168 hasRelatedWork W4253007864 @default.
- W2013140168 hasVolume "64" @default.
- W2013140168 isParatext "false" @default.
- W2013140168 isRetracted "false" @default.
- W2013140168 magId "2013140168" @default.
- W2013140168 workType "article" @default.