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- W2013148510 abstract "Abstract Transition metal(II) complexes of the cycloserine derivative, N 4,N′ 4-tereftalbis(cycloserine) or Terizidone, were prepared and investigated by means of magnetic measurements, electronic and infrared spectroscopy and conductivity measurements. The magnetic moments and electronic spectra of the Co(II) compounds are consistent with pseudotetrahedral and pseudooctahedral symmetries, whereas the Ni(II) complexes had a pseudotetrahedral geometry. The various ligand field parameters Dq, B′ and β have been evaluated; the B′ values suggest a strong covalency in the metal-ligand σ bond and the Dq values show a medium-strong ligand field. The position and multiplicity of the metal-halide stretching frequencies are discussed and used as a guide to the stereochemistry. Tetrahedral and octahedral structures are present in the zinc(II) and cadmium(II) complexes. The ligand was monodentate O-bonded or bidentate O,O′-bonded through the oxygen of the keto groups. We have never observed a metal-induced cycloserin..." @default.
- W2013148510 created "2016-06-24" @default.
- W2013148510 creator A5006509101 @default.
- W2013148510 creator A5018007259 @default.
- W2013148510 date "1980-11-01" @default.
- W2013148510 modified "2023-09-26" @default.
- W2013148510 title "CYCLOSERINE DERIVATIVES AS LIGANDS. COBALT(II), NICKEL(II), COPPER(II), ZINC(II) AND CADMIUM(II) HALIDE COMPLEXES OF N 4,N′ 4-TEREFTAL-BIS(CYCLOSERINE)" @default.
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- W2013148510 doi "https://doi.org/10.1080/00958978008079864" @default.
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