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• W2013153993 abstract "The tendency of Eu3+ in a crystal to attract an electron from the surrounding ligands and become Eu2+ can be represented by a six-body operator acting within the configuration 4f6. The matrix elements of this operator within any configuration 4fN with N>6 are expressible in terms of those of the unit tensors U(k) and the double tensor V(1k). This mechanism of charge transfer generally acts in a sense opposite to that of the spin correlated crystal field. This provides a possible source for the anomalous crystal-field splittings of Ho3+ 4f10 3KJ as well as the abrupt decline in the sixth-rank crystal-field parameters in passing from Eu3+ to Tb3+ in the LaCl3 lattice." @default.
• W2013153993 created "2016-06-24" @default.
• W2013153993 creator A5054813965 @default.
• W2013153993 date "1980-05-20" @default.
• W2013153993 modified "2023-09-26" @default.
• W2013153993 title "Charge transfer and crystal-field theory for rare-earth ions" @default.
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• W2013153993 doi "https://doi.org/10.1088/0022-3719/13/14/011" @default.
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