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- W2013155725 abstract "The first asymmetric synthesis of the trans-3,4-dimethyl-4-arylpiperidine opioid antagonist scaffold is reported. C-3 stereochemistry was established via CBS reduction and stereoselective anti-SN2‘ cuprate displacement of the derived allylic phosphonate. The resultant vinyl bromide was then elaborated to the target compound by Suzuki coupling and trans-selective 4-methylation. Extension of this methodology should allow general enantioselective access to highly substituted piperidine ring systems." @default.
- W2013155725 created "2016-06-24" @default.
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- W2013155725 date "2008-01-29" @default.
- W2013155725 modified "2023-09-26" @default.
- W2013155725 title "ChemInform Abstract: First Asymmetric Synthesis of trans-3,4-Dimethyl-4-arylpiperidines." @default.
- W2013155725 cites W2949282053 @default.
- W2013155725 doi "https://doi.org/10.1002/chin.200805140" @default.
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