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- W2013156621 abstract "Reactions of phosphonium ylides (4-MeC6H4)3PCHC(O)(2-C4H3S) (tptpy), Ph3PCHC(O)(2-C4H3O) (fppy), and (4-MeC6H4)3PCHC(O)(4-BrC6H4) (bbtppy) with HgX2 (X=Cl, Br, and I) in equimolar ratios in MeOH as solvent leads to the binuclear products 1–3 (Scheme 1). The bridge-splitting reaction of the binuclear complex [{HgI2(bbtppy)}2] (3c) by DMSO yields the mononuclear complex [HgI2⋅(bbtppy) (DMSO)] (3d) (Scheme 2). This bridge-splitting reaction can also be a method for the synthesis of mononuclear products. C-Coordination of the ylide and O-coordination of DMSO are demonstrated by a single-crystal X-ray-analysis of the mononuclear complex 3d. Characterization of the obtained compounds was also performed by means of elemental analysis and IR and 1H-, 31P-, and 13C-NMR spectroscopy. A theoretical study of some HgII complexes with phosphonium ylides is also reported." @default.
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- W2013156621 date "2010-06-15" @default.
- W2013156621 modified "2023-09-27" @default.
- W2013156621 title "Synthesis of New Phosphonium Ylides Containing Thiophene and Furan Rings and Study of Their Reaction with Mercury(II) Halides: Spectral and Structural Characterization" @default.
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- W2013156621 doi "https://doi.org/10.1002/hlca.200900305" @default.
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