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- W2013156650 abstract "Solid ternary complexes of the type M(TTA)2·TOPO (M = Zn2+ and Cu2+, TTA = thenoyltrifluoroacetone anion and TOPO = tri-n-octyl phosphine oxide) have been prepared and investigated. The phosphorus nuclear magnetic resonance method has been used to determine the equilibrium constant of the reaction Zn(TTA)2 (org.) + TOPO (org.) = Zn(TTA)2·TOPO(org.). This was found to be approximately 10 1/mole in anhydrous carbon tetrachloride medium. It was also shown that in the same medium, the less basic TBEP (tri-n-butoxyethyl phosphate) did not coordinate with Zn(TTA)2 to any measurable extent. In fact, the corresponding ternary complexes M(TTA)2·TBEP could not be isolated. Proton magnetic resonance studies also afford evidence for the reaction: Zn(TTA)2·2H2O + TOPO = Zn(TTA)2·TOPO + 2H2O in carbon tetrachloride medium. It is suggested that the phenomenon of synergism may be due to the enhanced solubility (in the organic phase) of neutral metal chelates caused by adduct formation with ligands such as TOPO." @default.
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- W2013156650 date "1965-02-01" @default.
- W2013156650 modified "2023-09-25" @default.
- W2013156650 title "Metal complexes involved in solvent extraction and their role in the synergistic effect" @default.
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- W2013156650 doi "https://doi.org/10.1016/0022-1902(65)80360-8" @default.
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