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- W2013159374 abstract "Coaxially polymerized, peripherally substituted derivatives of phthalocyanine (-[SiPc(CnH2n+ 1)8-O-]; n = 8, 12) have been synthesized and characterized. They display efficient energy-migration properties and a dark conductivity at room temperature of 2 × 10−2 S · m−1, even in the absence of dopants. The temperature dependence of the conductivity for the C8 derivative, over the range - 50 to + 200°C, is given, to a good approximation, by σ = 1.5 · exp [- Ea/(kB · T)] S · m−1 with an activation energy Ea of 0.11 eV (2.5 kcal/mole). This material could be an example of an intrinsic, one-dimensional conducting polymer." @default.
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- W2013159374 date "1990-01-01" @default.
- W2013159374 modified "2023-09-26" @default.
- W2013159374 title "Synthesis and transport properties of rigid poly(octasubstituted phthalocyaninatosiloxanes)" @default.
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- W2013159374 doi "https://doi.org/10.1002/recl.19901090314" @default.
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