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- W2013161874 abstract "The preparation of ( S )-2-cyanopiperidine 4 provides a new access to 2-substituted piperidines. This synthesis is based on an enantioselective ( R )-oxynitrilase-catalyzed reaction for the preparation of ( R )-(+)-6-bromo-2-hydroxyhexanenitrile 1 and the subsequent cyclization of this compound to yield the piperidine ring. The utilization of 4 as the starting material for the synthesis of ( S )-2-aminomethylpiperidine 6 , ( R )-(−)-coniine 10 and ( S )-(−)-pipecolic acid 13 is also described." @default.
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- W2013161874 date "1998-05-01" @default.
- W2013161874 modified "2023-09-27" @default.
- W2013161874 title "Chemoenzymatic synthesis of (S)-2-cyanopiperidine, a key intermediate in the route to (S)-pipecolic acid and 2-substituted piperidine alkaloids" @default.
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- W2013161874 doi "https://doi.org/10.1016/s0957-4166(98)00140-2" @default.
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