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• W2013162487 endingPage "8801" @default.
• W2013162487 startingPage "8801" @default.
• W2013162487 abstract "Treatment of Co3(μ3-CCCR)(μ-dppm)(CO)7 with O2 (air) in the presence of [FcH]PF6 afforded Co3{μ3-CC(O)R}(μ-dppm)(CO)7 by the formal conversion –CC– + O–O → >C–O + CO. In this way, complexes with R = Ph, Fc, and W(CO)3Cp, bis-clusters {Co3(μ-dppm)(CO)7}2{μ3:μ3-[C(O)(CC)C]}, {Co3(μ-dppm)(CO)7}2{μ3:μ3-[C(O)(CC)xC(O)C]} (x = 1, 2), and {Co3(μ-dppm)(CO)7}2{μ3:μ3-[CC(O)CCC6H4CCC(O)C]}, and heterometallic bis-clusters {Co3(μ-dppm)(CO)7}{μ3:μ3-[CC(O)CCC]}{M3(μ-H)3(CO)9} (M = Ru, Os) have been prepared. Single-crystal XRD structure determinations of several products are reported together with that of precursor {Co3(μ-dppm)(CO)7}2{μ3:μ3-[C(CC)2C6H4(CC)2C]}." @default.
• W2013162487 created "2016-06-24" @default.
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• W2013162487 date "2010-01-01" @default.
• W2013162487 modified "2023-09-26" @default.
• W2013162487 title "Conversion of CC to CO in alkynyl-metal complexes: oxidation of carbon chains capped by carbon-tricobalt clusters" @default.
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• W2013162487 doi "https://doi.org/10.1039/c002997c" @default.
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