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- W2013163610 abstract "Apparent molar volumes Vϕ,B of n-propylamine, n-butylamine, di-n-propylamine, di-n-butylamine, triethylamine, tri-n-propylamine, and tri-n-butylamine in 1-butanol and 2-butanol at 303.15 K have been determined with high precision vibrating tube Anton Paar densimeter (model DMA 60/602). From these data limiting partial molar volumes VB∞ and limiting excess partial molar volumes V_̄BE,∞ were estimated. The results are analysed and interpreted in terms of solute–solvent interactions and structural effects of the molecules. An attempt to find a measure of the contribution of the specific interactions to the partial molar volumes of primary, secondary and tertiary amines in 1-butanol and 2-butanol was made using Terasawa model, hard-sphere theory (HST) and scaled particle theory (SPT). The ERAS model has also been applied to estimate apparent molar volumes, and excess apparent molar volumes of alkylamine solutions in 1-butanol and 2-butanol. The results agree well in the different approaches used." @default.
- W2013163610 created "2016-06-24" @default.
- W2013163610 creator A5014226661 @default.
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- W2013163610 date "2009-02-01" @default.
- W2013163610 modified "2023-10-02" @default.
- W2013163610 title "Studies of partial molar volumes of alkylamine in non-electrolyte solvents III: Alkyl amines in butanols at 303.15 K" @default.
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- W2013163610 doi "https://doi.org/10.1016/j.molliq.2008.07.014" @default.
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