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- W2013174080 abstract "The thermodynamic properties of the Nasicon solid solution system (Na1+xZr2SixPx−3O12, 0<-x<-3) have been investigated by measuring the cell voltage of a solid state galvanic cell (500K<T<1000)K) and by determination of the specific heats (4 K<T<800 K). The entropies and formation enthalpies are calculated for the whole x and T range under consideration. The agreement between the calorimetric entropies and those obtained by the electrochemical method are very good. The result that the solid solution system according to Hong's composition formula is intrinsically stable, is confirmed by the preparation process and by sinter tests. The thermodynamics of the system can be expressed in terms of a mixture model. The thermodynamic stabilities against Na are calculated for different compositions." @default.
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- W2013174080 date "1986-01-01" @default.
- W2013174080 modified "2023-10-12" @default.
- W2013174080 title "Thermodynamic and electrochemical investigations of the Nasicon solid solution system" @default.
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- W2013174080 doi "https://doi.org/10.1016/0167-2738(86)90294-8" @default.
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