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- W2013174934 abstract "Abstract Stoichiometric reduction of the C,N double bond of oxime precursors of α-amino acids was performed in aqueous media by Cr(II) complexes of natural amino acids. The reduction of oximes of α-ketophenylacetic, α-keto-β-phenylpropionic and α-ketopropionic acids proceeded up to >90% conversion and 2–30% enantiomeric excess. 1:2 complexes of Cr(II) with l -alanine, l -valine, l -aspartic acid, l -histidine and l -phenylalanine were used as reducing agents. The reduction of α-(oximino)phenylacetic acid showed increasing e.e. (and decreasing conversion) with increasing temperature." @default.
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- W2013174934 date "2003-10-01" @default.
- W2013174934 modified "2023-10-14" @default.
- W2013174934 title "Asymmetric synthesis of amino acids by Cr(II) complexes of natural amino acids" @default.
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- W2013174934 doi "https://doi.org/10.1016/s0022-328x(03)00775-7" @default.
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