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- W2013175587 abstract "Abstract A number of linear cumulenes and heterocumulenes have been made by charge stripping of anions of known bond connectivity in the source of a mass spectrometer. Some of these reactive molecules have been identified in interstellar molecular clouds. The structures of these neutrals may be investigated by reionization to a decomposing positive ion [the neutralization–reionization technique ( − NR + )], and/or by ab initio calculations. Energized linear cumulenes and heterocumulenes may undergo cyclization to form stable cyclic isomers. To cite a selection of the examples described in this review: (i) four‐atom systems CCCC and some heterocumulenes CCCX (X = B, N, Al, Si, P) involve the formation of stable four‐membered ring rhombic (also called kite and fan) structures. One of the cyclic molecules, cyclo‐C 3 Si, has been detected in interstellar molecular clouds, (ii) five‐atom cumulene and heterocumulene systems are more complex. Linear CCCCC rearranges the carbon skeleton by forming a C substituted rhomboid system, CCCCO forms a three‐membered cyclic isomer, while nitrogen containing five‐atom cumulenes effect nitrile to isonitrile interconversion via three‐centered cyclized intermediates, and (iii) CCCCCC and CCCCBO cyclize to give unique six‐membered ring systems. © 2010 Wiley Periodicals, Inc., Mass Spec Rev 30:1225–1241, 2011" @default.
- W2013175587 created "2016-06-24" @default.
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- W2013175587 date "2011-03-11" @default.
- W2013175587 modified "2023-09-27" @default.
- W2013175587 title "Studies of cyclization reactions of linear cumulenes and heterocumulenes using the neutralization–reionization procedure and/or ab initio calculations" @default.
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- W2013175587 doi "https://doi.org/10.1002/mas.20328" @default.
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