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- W2013180314 abstract "The kinetics of the oxidation of Sb(III) by Ce(IV) conform to the expression −d[Ce(IV)]Dt=2kK4[Ce(IV)][Sb(III)][Cl−][H+]K3K2[HSO4−]2(1 + K4[Cl]) in ∼ 1–2 M H2SO4 and at chloride ion concentration ⩽ 0·1 M. The active Ce(IV) species is CeSO4++, which further complexes with chloride ion. The magnitude of the Arrhenius parameters is suggestive of an electron-transfer reaction. The mechanism is discussed in accordance with a chloride ion bridge activated transition state where the chlorine atom is probably transferred from (CeSO4Cl)+ to Sb(III). Rates of other halide-activated reactions have been compared and it is seen that most polarizable atom is transferred most easily. Mn(II) catalyses the reaction, the course of which is completely changed. The active species of SB(III) is also discussed." @default.
- W2013180314 created "2016-06-24" @default.
- W2013180314 creator A5019727123 @default.
- W2013180314 creator A5072190201 @default.
- W2013180314 date "1968-11-01" @default.
- W2013180314 modified "2023-09-23" @default.
- W2013180314 title "Kinetics and mechanism of the oxidation of Sb(III) by Ce(IV) in sulphuric acid solution in presence of chloride ion." @default.
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- W2013180314 doi "https://doi.org/10.1016/0022-1902(68)80159-9" @default.
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