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- W2013183763 abstract "Abstract Kinetic experiments with homodisperse seeds of various particle size verified the previous results as to the effect of particle number, degree of conversion, and initiator concentration on the rate of polymerization. Also, experiments with mixed seeds consisting of two sets of homodisperse particles of different sizes were carried out and the relative growth of the particles was measured. A mathematical model involving desorption and reabsorption of radicals into particles was developed for such competitive growth experiments and applied to describe the experimental results. Experiments with mixed emulsifier systems consisting of an anionic emulsifier and different fatty alcohols in seed polymerization supported previous results regarding the effect of fatty alcohol on the rate of reaction. The application of certain systems of anionic emulsifier and fatty alcohol led to a much more effective emulsification of the monomer. It is suggested that in this case the monomer droplets may serve as loci for initiation and polymerization." @default.
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- W2013183763 date "1973-01-01" @default.
- W2013183763 modified "2023-10-18" @default.
- W2013183763 title "Studies on the emulsion polymerization of vinyl chloride by seed polymerization" @default.
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- W2013183763 doi "https://doi.org/10.1002/polc.5070420154" @default.
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