FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2013184597> ?p ?o ?g. }

• W2013184597 endingPage "12606" @default.
• W2013184597 startingPage "12603" @default.
• W2013184597 abstract "The cysteine anion was produced in the gas phase by electrospray ionization and investigated by photoelectron spectroscopy at low temperature (70 K). The cysteine anion was found to exhibit the thiolate form [-SCH2CH(NH2)CO2H], rather than the expected carboxylate form [HSCH2CH(NH2)CO2-]. This observation was confirmed by two control experiments, that is, methyl cysteine [CH3SCH2CH(NH2)CO2-] and cysteine methyl ester [-SCH2CH(NH2)CO2CH3]. The electron binding energy of [-SCH2CH(NH2)CO2H] was measured to be about 0.7 eV blue-shifted relative to [-SCH2CH(NH2)CO2CH3] due to the formation of an intramolecular -S-...HO2C- hydrogen bond in the cysteine thiolate. Theoretical calculations at the CCSD(T)/6-311++G(2df,p) and B3LYP/6-311++G(2df,p) levels were carried out to estimate the strength of this intramolecular -S-...HO2C- hydrogen bond. Combining experimental measurements and theoretical calculations yielded an estimated value of 16.4 +/- 2.0 kcal/mol for the -S-...HO2C- intramolecular hydrogen-bond strength." @default.
• W2013184597 created "2016-06-24" @default.
• W2013184597 creator A5006670588 @default.
• W2013184597 creator A5028098042 @default.
• W2013184597 creator A5053967127 @default.
• W2013184597 creator A5062786033 @default.
• W2013184597 date "2006-10-31" @default.
• W2013184597 modified "2023-10-14" @default.
• W2013184597 title "Observation of Cysteine Thiolate and ^-S···H−O Intermolecular Hydrogen Bond" @default.
• W2013184597 cites W1966964730 @default.
• W2013184597 cites W1977664548 @default.
• W2013184597 cites W1981575136 @default.
• W2013184597 cites W1983901754 @default.
• W2013184597 cites W1993477570 @default.
• W2013184597 cites W2004517651 @default.
• W2013184597 cites W2006466448 @default.
• W2013184597 cites W2010790627 @default.
• W2013184597 cites W2011399788 @default.
• W2013184597 cites W2019900547 @default.
• W2013184597 cites W2024487566 @default.
• W2013184597 cites W2025468090 @default.
• W2013184597 cites W2031208521 @default.
• W2013184597 cites W2033097620 @default.
• W2013184597 cites W2033711082 @default.
• W2013184597 cites W2036928117 @default.
• W2013184597 cites W2043701998 @default.
• W2013184597 cites W2049281887 @default.
• W2013184597 cites W2067237929 @default.
• W2013184597 cites W2067887310 @default.
• W2013184597 cites W2084953881 @default.
• W2013184597 cites W2089998300 @default.
• W2013184597 cites W2096921126 @default.
• W2013184597 cites W2099918432 @default.
• W2013184597 cites W2106334513 @default.
• W2013184597 cites W2139294517 @default.
• W2013184597 cites W2143981217 @default.
• W2013184597 cites W2147304506 @default.
• W2013184597 cites W2149202053 @default.
• W2013184597 cites W2165813993 @default.
• W2013184597 cites W2168817118 @default.
• W2013184597 cites W4255994466 @default.
• W2013184597 cites W4302777425 @default.
• W2013184597 doi "https://doi.org/10.1021/jp0643799" @default.
• W2013184597 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/17107110" @default.
• W2013184597 hasPublicationYear "2006" @default.
• W2013184597 type Work @default.
• W2013184597 sameAs 2013184597 @default.
• W2013184597 citedByCount "51" @default.
• W2013184597 countsByYear W20131845972012 @default.
• W2013184597 countsByYear W20131845972013 @default.
• W2013184597 countsByYear W20131845972014 @default.
• W2013184597 countsByYear W20131845972015 @default.
• W2013184597 countsByYear W20131845972016 @default.
• W2013184597 countsByYear W20131845972017 @default.
• W2013184597 countsByYear W20131845972018 @default.
• W2013184597 countsByYear W20131845972019 @default.
• W2013184597 countsByYear W20131845972020 @default.
• W2013184597 countsByYear W20131845972021 @default.
• W2013184597 countsByYear W20131845972022 @default.
• W2013184597 crossrefType "journal-article" @default.
• W2013184597 hasAuthorship W2013184597A5006670588 @default.
• W2013184597 hasAuthorship W2013184597A5028098042 @default.
• W2013184597 hasAuthorship W2013184597A5053967127 @default.
• W2013184597 hasAuthorship W2013184597A5062786033 @default.
• W2013184597 hasConcept C112887158 @default.
• W2013184597 hasConcept C121332964 @default.
• W2013184597 hasConcept C145148216 @default.
• W2013184597 hasConcept C147597530 @default.
• W2013184597 hasConcept C166950319 @default.
• W2013184597 hasConcept C178790620 @default.
• W2013184597 hasConcept C181199279 @default.
• W2013184597 hasConcept C184779094 @default.
• W2013184597 hasConcept C185592680 @default.
• W2013184597 hasConcept C2778074193 @default.
• W2013184597 hasConcept C2779201268 @default.
• W2013184597 hasConcept C32909587 @default.
• W2013184597 hasConcept C40684141 @default.
• W2013184597 hasConcept C512968161 @default.
• W2013184597 hasConcept C54516573 @default.
• W2013184597 hasConcept C62520636 @default.
• W2013184597 hasConcept C71240020 @default.
• W2013184597 hasConcept C75079739 @default.
• W2013184597 hasConcept C8010536 @default.
• W2013184597 hasConcept C93282013 @default.
• W2013184597 hasConceptScore W2013184597C112887158 @default.
• W2013184597 hasConceptScore W2013184597C121332964 @default.
• W2013184597 hasConceptScore W2013184597C145148216 @default.
• W2013184597 hasConceptScore W2013184597C147597530 @default.
• W2013184597 hasConceptScore W2013184597C166950319 @default.
• W2013184597 hasConceptScore W2013184597C178790620 @default.
• W2013184597 hasConceptScore W2013184597C181199279 @default.
• W2013184597 hasConceptScore W2013184597C184779094 @default.
• W2013184597 hasConceptScore W2013184597C185592680 @default.
• W2013184597 hasConceptScore W2013184597C2778074193 @default.
• W2013184597 hasConceptScore W2013184597C2779201268 @default.
• W2013184597 hasConceptScore W2013184597C32909587 @default.
• W2013184597 hasConceptScore W2013184597C40684141 @default.
• W2013184597 hasConceptScore W2013184597C512968161 @default.

• next