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- W2013189950 abstract "The purpose of this paper is to study the glass formation tendency in the ternary system B2O3―Bi2O3―MoO3 and to define the main structural units building the amorphous network. A wide glass formation area was determined which is situated near the Bi2O3―B2O3 side. A liquid phase separation region was observed near the MoO3―B2O3 side for compositions containing below 25 mol% Bi2O3 and their microheterogeneous structure was observed by SEM. The phase formation was characterized by X-ray diffraction (XRD). By DTA was established the glass transition temperature (Tg) in the range of 380–420 °C and crystallization temperature (Tx) vary between 420 and 540 °C. The main building units forming the amorphous network are BO3 (1270 and 1200 cm− 1), BO4 (930–880, 1050–1040 cm− 1), MoO4 (840–760 cm− 1) and BiO6 (470 cm− 1). It was proved that Bi2O3 favors the BO3 → BO4 transformations while MoO3 preserves BO3 units in the amorphous network." @default.
- W2013189950 created "2016-06-24" @default.
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- W2013189950 date "2011-07-01" @default.
- W2013189950 modified "2023-09-25" @default.
- W2013189950 title "Glass formation and structure of glasses in B2O3―Bi2O3―MoO3 system" @default.
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- W2013189950 doi "https://doi.org/10.1016/j.jnoncrysol.2010.12.056" @default.
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