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- W2013194699 abstract "Photolysis of [CpMo(CO)3Cl] in the presence of 2-(1-propenyl)phenyldiphenylphosphane (PP, cis/trans mixture) yields the complex [CpMo(CO)Cl(PP)], 2, with an olefin ligand tethered to a phosphorus donor atom. A trans configuration of the substituents at the olefinic unit is thermodynamically preferred, so that the corresponding complex 2t can be isolated in isomerically pure form under certain conditions. However, the cis-olefin complex 2c has been characterized in its mixture with 2t, too. Treatment of 2t with HNMe2 leads to the intramolecular elimination of HCl under formation of the compound [CpMo(CO)(CH2CHCHC6H4PPh2)], 3, bearing a chelating π-allyl/PPh2 ligand. When a CH2Cl2 solution of 3 is photolyzed in the presence of N2O, the CO ligand is replaced by two chloride ligands, i.e., the Mo center is oxidized to the oxidation state +IV. The resulting complex [CpMoCl2(CH2CHCHC6H4PPh2)], 4, is one of the rare examples, where a soft allyl ligand is bound to a metal center in a comparatively high oxidation state. However, probably due to the chelate effect, the Mo−allyl bond is remarkably stable. All compounds 2−4 have been investigated by means of single-crystal X-ray diffraction, and their crystal structures are discussed." @default.
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- W2013194699 date "2001-04-01" @default.
- W2013194699 modified "2023-09-24" @default.
- W2013194699 title "Syntheses of Molybdenum(II) and Molybdenum(IV) Complexes Bearing Tethered Homoallylic Phosphines" @default.
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- W2013194699 doi "https://doi.org/10.1021/om001065d" @default.
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