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• W2013213104 abstract "Steady state S2–S0 and S1–S0 absorption and emission spectra and picosecond S2 decay and S1 fluorescence rise times have been measured for the model porphyrin ZnTPPS4− in water and in aqueous iodide solutions of constant ionic strength. The dynamics of S1 quenching by iodide are well-modeled by a Stern–Volmer mechanism yielding kQ = 1.75 × 109 M−1 s−1. The S2 state is quenched on a ps time scale by a static electron-transfer mechanism at an average donor–acceptor separation of 0.38 nm. The implications of these data for dye-sensitized solar cells that employ I−/I3− as the redox medium are discussed." @default.
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• W2013213104 date "2011-01-01" @default.
• W2013213104 modified "2023-10-18" @default.
• W2013213104 title "Photophysics and halide quenching of Soret-excited ZnTPPS4− in aqueous media" @default.
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• W2013213104 doi "https://doi.org/10.1016/j.cplett.2010.11.010" @default.
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