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- W2013218144 abstract "Morphological characters and multi-element isotopic compositions of carbonates from the loess–paleosol sequences in Northwestern China are examined to explore the origin of the minerals. Samples are collected from various sections ranging from Holocene to 0.9 Ma within the sequences and fractions with grain sizes >45 and <2 μm are separated from the bulk soil and examined by SEM and TEM. The results show that the grains >45 μm exhibit an almost perfect spherical shape while those <2 μm are dominated by nano-rods having diameters of 30–50 nm and lengths of 0.3–2 μm, presumably indicating the detrital origin of the coarse fractions and the authigenic characters of the fine ones. Such implications are corroborated by the multi-elemental isotopic compositions of the carbonate minerals. A comparison of the δ13C and δ18O values between minerals and biologically originated samples indicates that the <2 μm fractions have a similar composition to those of coexisting land snail shells. Additional differences between the two size fractions also manifest in the ratios of 206Pb/204Pb, 207Pb/204Pb, 208Pb/204Pb, and 87Sr/86Sr. These results suggest the utility of fine carbonate particles in the soil profile in reconstructing a potentially higher resolution δ13C and δ18O time series to elucidate the paleoclimatic fluctuation in the Chinese Loess Plateau during Pleistocene. The discovery of the nano-rod calcite in Chinese loess, together with previous findings of the similar mineral form in Asian dust, strongly suggests the possibility that these highly reactive CaCO3 form may alter the aerosol properties during transport." @default.
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- W2013218144 date "2008-09-01" @default.
- W2013218144 modified "2023-09-27" @default.
- W2013218144 title "Morphological characters and multi-element isotopic signatures of carbonates from Chinese loess–paleosol sequences" @default.
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- W2013218144 doi "https://doi.org/10.1016/j.gca.2008.06.024" @default.
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