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- W2013229454 abstract "An equation of state for chain fluids has been derived through the r-particle cavity-correlation function (CCF) for chains obtained from sticky spheres; here r is the chain length. The r-particle CCF is approximated by a product of effective two-particle CCFs, accounting for nearest-neighbor correlations and next-to-nearest-neighbor correlations. For hard-sphere chain fluids (HSCF), the density dependence for nearest-neighbor effective two-particle CCFs is determined by the equation of Tildesley–Streett for hard-sphere dumbbells and that for next-to-nearest-neighbor effective two-particle CCFs by computer-simulation results for hard-sphere trimers. The final equation of state has a simple form which gives compressibility factors and second virial coefficients for homonuclear HSCFs covering a wide range of chain length (up to r=201) in excellent agreement with computer simulations. Satisfactory comparisons are also obtained between predicted and computer-simulation results for homonuclear HSCF mixtures, HSCFs containing side-chains and rings, and heteronuclear HSCFs (copolymers)." @default.
- W2013229454 created "2016-06-24" @default.
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- W2013229454 date "1996-01-01" @default.
- W2013229454 modified "2023-10-16" @default.
- W2013229454 title "Equation of state for fluids containing chainlike molecules" @default.
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- W2013229454 doi "https://doi.org/10.1063/1.470838" @default.
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