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• W2013248422 abstract "A model of the rotational motion of water molecules within ion hydration sheaths is proposed in the present paper. This model is based on the concept of a ‘boundary’ ion, according to which the parameters of the structural surroundings, as well as the translational, rotational and librational motions of water molecules within the first sphere, are the same as those for water molecules in water. The wide-band absorption spectra, α(ν)(0 < ν/cm–1 < 400), and the complex dielectric permittivity spectrum measured for the concentrated electrolyte solutions, are described on the basis of the model proposed in this paper. It is shown that the confined rotator/extended diffusion (CR/ED) model, which has been advanced previously for liquid water, is applicable for spectral calculations of the electrolyte solutions studied in the present paper." @default.
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• W2013248422 date "1993-01-01" @default.
• W2013248422 modified "2023-09-25" @default.
• W2013248422 title "Orientational relaxation in hydrogen-bonded systems: aqueous solutions of electrolytes" @default.
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• W2013248422 doi "https://doi.org/10.1039/ft9938901985" @default.
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