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- W2013258263 abstract "(C2H5)2NSF3 (1b) und (C2H5)2NS(O)F3 (2b) erhält man bei der Umsetzung von (C2H5)2NSi(CH3)3 (7) mit SF4 bzw. OSF4. Die beobachteten und berechneten 19F-NMR-Spektren von (CH3)2NS(O)F3 (2a) und 2b machen eine trigonal-bipyramidale Struktur wahrscheinlich. Verbindungen vom Typ R2NSF3 (1) (R = CH3 oder C2H5) reagieren mit Bis(trimethylsilyl)-carbodiimid (8) zu Aminoschwefelmonofluoridimiden NCNS(F)NR2 (5), den ersten Vertretern dieser bisher unbekannten Substanzklasse. In ähnlicher Weise gewinnt man aus R2NS(O)F3 (2) und 8 die Aminoschwefeloxidmonofluoridimide NCN S(O)(F)NR2 (6). Preparation of new Aminosulfur Monofluoride Imides and Aminosulfur Oxide Monofluoride Imides and the Structure of Aminosulfur Oxide Trifluorides (C2H5)2NSF3 (1b) and (C2H5)2NS(O)F3 (2b) are formed in the reaction of (C2H5)2NSi(CH3)3 (7) with SF4 and OSF4, respectively. The observed and calculated 19F n.m.r. spectra of (CH3)2NS(O)F3 (2a) and 2 b suggest trigonal bipyramidal structure for both substances. Compounds of the type R2NSF3 (1) (RCH3 or C2H5) react with bis(trimethylsilyl)-carbodiimide (8) yielding the previously unknown aminosulfur monofluoride imides NCNS(F)NR2 (5). In a similar manner the reaction of R2NS(O)F3 (2) with 8 gives aminosulfur oxide monofluoride imides NCNS(O)(F)NR2 (6)." @default.
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- W2013258263 title "Darstellung neuer Aminoschwefelmonofluoridimide und ‐oxidmonofluoridimide sowie über die Struktur der Aminoschwefeloxidtrifluoride" @default.
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- W2013258263 doi "https://doi.org/10.1002/cber.19701030231" @default.
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