Matches in SemOpenAlex for { <https://semopenalex.org/work/W2013259969> ?p ?o ?g. }
Showing items 1 to 100 of
100
with 100 items per page.
- W2013259969 endingPage "839" @default.
- W2013259969 startingPage "821" @default.
- W2013259969 abstract "Calorimetric enthalpies of reaction have been measured for the overall biochemical reaction{pyrophosphate(aq) + H2O(l) = 2phosphate (aq)} . The reaction was catalyzed by alkaline phosphatase and, to simplify the thermochemistry, was carried out in the absence of Mg 2 + (aq). Measurements were performed with phosphate buffer ( pH = 7.19 and 7.94), PIPES buffer ( pH = 7.13), and HEPES buffer ( pH = 7.86). The results of these measurements were analyzed by using an equilibrium model. These calculations lead to the standard molar enthalpy changeΔrHmo = − (17.3 ± 0.6)kJ·mol − 1 (temperature T = 298.15 K and ionic strengthI = 0) for the reference reaction{HP2O73 − (aq) + H2O(l) = 2HPO42 − (aq) + H + (aq)} . Values of the apparent equilibrium constantK′ for the overall biochemical reaction from the literature were also analyzed by using the equilibrium model in order to obtain what is believed to be a reliable value for the equilibrium constantK = 4.7 · 10 − 4 for the reference reaction. The values ofK and ΔrHmo for the reference reaction have been used together with values from the CODATA tables to calculate standard molar formation properties for the pyrophosphate species." @default.
- W2013259969 created "2016-06-24" @default.
- W2013259969 creator A5018714166 @default.
- W2013259969 creator A5068420359 @default.
- W2013259969 date "2002-06-01" @default.
- W2013259969 modified "2023-10-16" @default.
- W2013259969 title "Thermochemistry of the biochemical reaction: { pyrophosphate(aq) + H2O(l) = 2 phosphate(aq)}" @default.
- W2013259969 cites W1518690394 @default.
- W2013259969 cites W1563380435 @default.
- W2013259969 cites W1565811533 @default.
- W2013259969 cites W1595805083 @default.
- W2013259969 cites W190854452 @default.
- W2013259969 cites W1954122564 @default.
- W2013259969 cites W1973266360 @default.
- W2013259969 cites W1973734905 @default.
- W2013259969 cites W1999147319 @default.
- W2013259969 cites W2012149628 @default.
- W2013259969 cites W2012966727 @default.
- W2013259969 cites W2021600340 @default.
- W2013259969 cites W2034106364 @default.
- W2013259969 cites W2035910211 @default.
- W2013259969 cites W2037778165 @default.
- W2013259969 cites W2049003507 @default.
- W2013259969 cites W2053614035 @default.
- W2013259969 cites W2055214793 @default.
- W2013259969 cites W2061002857 @default.
- W2013259969 cites W2068341638 @default.
- W2013259969 cites W2074487612 @default.
- W2013259969 cites W2128802238 @default.
- W2013259969 cites W2140491206 @default.
- W2013259969 cites W2312288869 @default.
- W2013259969 cites W2314811272 @default.
- W2013259969 cites W2327834198 @default.
- W2013259969 cites W2332422106 @default.
- W2013259969 cites W2434798149 @default.
- W2013259969 cites W3023691417 @default.
- W2013259969 cites W2020558092 @default.
- W2013259969 doi "https://doi.org/10.1006/jcht.2002.0931" @default.
- W2013259969 hasPublicationYear "2002" @default.
- W2013259969 type Work @default.
- W2013259969 sameAs 2013259969 @default.
- W2013259969 citedByCount "11" @default.
- W2013259969 countsByYear W20132599692012 @default.
- W2013259969 countsByYear W20132599692020 @default.
- W2013259969 crossrefType "journal-article" @default.
- W2013259969 hasAuthorship W2013259969A5018714166 @default.
- W2013259969 hasAuthorship W2013259969A5068420359 @default.
- W2013259969 hasConcept C10710636 @default.
- W2013259969 hasConcept C121332964 @default.
- W2013259969 hasConcept C147368240 @default.
- W2013259969 hasConcept C147789679 @default.
- W2013259969 hasConcept C161790260 @default.
- W2013259969 hasConcept C178790620 @default.
- W2013259969 hasConcept C179104552 @default.
- W2013259969 hasConcept C181199279 @default.
- W2013259969 hasConcept C185592680 @default.
- W2013259969 hasConcept C202189072 @default.
- W2013259969 hasConcept C2776043855 @default.
- W2013259969 hasConcept C29563950 @default.
- W2013259969 hasConcept C3288061 @default.
- W2013259969 hasConcept C57171237 @default.
- W2013259969 hasConcept C79289859 @default.
- W2013259969 hasConcept C97355855 @default.
- W2013259969 hasConceptScore W2013259969C10710636 @default.
- W2013259969 hasConceptScore W2013259969C121332964 @default.
- W2013259969 hasConceptScore W2013259969C147368240 @default.
- W2013259969 hasConceptScore W2013259969C147789679 @default.
- W2013259969 hasConceptScore W2013259969C161790260 @default.
- W2013259969 hasConceptScore W2013259969C178790620 @default.
- W2013259969 hasConceptScore W2013259969C179104552 @default.
- W2013259969 hasConceptScore W2013259969C181199279 @default.
- W2013259969 hasConceptScore W2013259969C185592680 @default.
- W2013259969 hasConceptScore W2013259969C202189072 @default.
- W2013259969 hasConceptScore W2013259969C2776043855 @default.
- W2013259969 hasConceptScore W2013259969C29563950 @default.
- W2013259969 hasConceptScore W2013259969C3288061 @default.
- W2013259969 hasConceptScore W2013259969C57171237 @default.
- W2013259969 hasConceptScore W2013259969C79289859 @default.
- W2013259969 hasConceptScore W2013259969C97355855 @default.
- W2013259969 hasIssue "6" @default.
- W2013259969 hasLocation W20132599691 @default.
- W2013259969 hasOpenAccess W2013259969 @default.
- W2013259969 hasPrimaryLocation W20132599691 @default.
- W2013259969 hasRelatedWork W1976143445 @default.
- W2013259969 hasRelatedWork W1987002508 @default.
- W2013259969 hasRelatedWork W1991066515 @default.
- W2013259969 hasRelatedWork W1998308621 @default.
- W2013259969 hasRelatedWork W2013259969 @default.
- W2013259969 hasRelatedWork W2369403632 @default.
- W2013259969 hasRelatedWork W2385055399 @default.
- W2013259969 hasRelatedWork W2392374266 @default.
- W2013259969 hasRelatedWork W2886657556 @default.
- W2013259969 hasRelatedWork W2977623733 @default.
- W2013259969 hasVolume "34" @default.
- W2013259969 isParatext "false" @default.
- W2013259969 isRetracted "false" @default.
- W2013259969 magId "2013259969" @default.
- W2013259969 workType "article" @default.