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- W2013267114 abstract "EPR studies were performed for NaY zeolite samples of the faujasite type with an Si/Al ratio of 2.56 with a part of the Na+ ions replaced by Cu2+. A six-stops pathway of Cu2+ migration in the faujasite network was postulated and the sites of copper complexes localization were determined vs the dehydration temperature varied from 25 to 400°C. Six different kinds of Cu2+ complexes appear successively in the dehydration process: a hexahydrate copper complex rotating freely within the supercage and localized complexes of different water content. EPR parameter analysis in terms of MO-theory indicated four kinds of six-coordinated Cu2+ complexes with the symmetry of tetragonally elongated octahedron (D4h) and two quasi-identical four-coordinated Cu2+ complexes of pseudotetrahedral symmetry (D2d)." @default.
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- W2013267114 date "1985-01-01" @default.
- W2013267114 modified "2023-10-16" @default.
- W2013267114 title "Migration and structure of aqueous Cu2+ complexes in faujasite" @default.
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- W2013267114 doi "https://doi.org/10.1016/0022-4596(85)90257-9" @default.
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