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• W2013272681 abstract "Isobaric vapor-liquid equilibrium data were measured at 74.66, 101.32 and 127.99 kPa for binary mixtures composed of methyl ethanoate or methyl propanoate and propan-2-ol using a dynamic method. In thermodynamic calcutions using the data, the vapor phase was considered to be non-ideal, and all the systems studied exhibit positive deviations from ideal solution behavior. At 74.66 kPa, the binary system (x1 methyl propanoate + x2 propan-2-ol) presents an azeotrope at x1 = 0.666, T = 340.47 K; as pressure increased, azeotrope concentration decreased quasi-regularly towards regions richer in propan-2-ol. After reduction of the data by fitting with a suitable equation and verification of thermodynamic consistency, various group-contribution models were applied to estimate the isobaric VLE data. The mean error in prediction of the activity coefficients for each system in no case exceeded 7%." @default.
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• W2013272681 date "1993-01-01" @default.
• W2013272681 modified "2023-10-17" @default.
• W2013272681 title "Vapor-liquid equilibria behavior of methyl esters and propan-2-ol at 74.66, 101.32 and 127.99 kPa." @default.
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• W2013272681 doi "https://doi.org/10.1252/jcej.26.259" @default.
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