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- W2013280705 endingPage "11171" @default.
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- W2013280705 abstract "Fellowship of the ring: The first total synthesis of (+)-crotogoudin, a 3,4-seco-atisane diterpenoid natural product, is reported. Asymmetric access to the bicyclo[2.2.2]octane core is achieved through a desymmetrization of a meso-diketone with baker's yeast (LG=leaving group, PG=protecting group). A SmI2 -induced radical cyclopropane-opening/annulation/elimination cascade affords the suitably decorated tetracyclic structure of (+)-crotogoudin. The synthesis led to revision of the reported optical rotation of the natural product and to assignment of its absolute configuration as an ent-atisane (5R,10R)." @default.
- W2013280705 created "2016-06-24" @default.
- W2013280705 creator A5049997686 @default.
- W2013280705 creator A5081483309 @default.
- W2013280705 date "2013-08-26" @default.
- W2013280705 modified "2023-09-27" @default.
- W2013280705 title "Total Synthesis of (+)-Crotogoudin" @default.
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- W2013280705 doi "https://doi.org/10.1002/anie.201305822" @default.
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