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- W2013285436 abstract "Comparative analyses of the Er3+ (4f11) crystal free-ion energy level structures in the Er2O3, Sc2O3, Y2O3, YAlO3, GdAlO3, SrMoO4, ThGeO4, CaWO4, YVO4, LuPO4, Er(OH)3, ErCl3·6H2O, Er(C2H5SO4)3 ·9H2O, Na3[Er(Oxydiacetate)3]2NaClO4·6H2O and Er(HCOO)3·2H2O systems are reported. These analyses are based on a uniform model Hamiltonian that includes 20 free-ion parameters which are defined as central field (EAVG), two-body electrostatic repulsion (F2,4,6), two-body configuration (α, β, γ), three-body configuration (T2,3,4,6,7,8), spin-orbit (ξ), spin—other-orbit (M0,2,4) and electrostatically correlated spin—orbit (P2,4,6) interactions. The systematic theoretical analysis of crystal free-ion levels results in a good correlation between calculated and observed energies. For example, comparison between the observed and calculated crystal free-ion levels of 13(Er:GdAlO3), 8(Er:YVO4), 8(Er:LuPO4) and 11(Er:ErES) yields RMS deviations of 12 cm-1, 2 cm-1, 4 cm-1 and 7 cm-1 respectively. The empirical crystal free-ion energy parameters derived from fitting experimental data with the model Hamiltonian are consistent. The effects of the crystalline hosts on the empirical parameters are examined." @default.
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- W2013285436 title "Crystal free-ion energy level analysis of Er3+ (4f11) in various crystal hosts-oxygen coordinated systems" @default.
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- W2013285436 doi "https://doi.org/10.1016/0921-4526(94)90008-6" @default.
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