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• W2013295008 abstract "Silica gels believed to be grafted with dithioacetal derivatives were recently used for Hg(II) extraction, and were found to selectively remove 94–100% of Hg 2+ ions from metal ion mixtures. The current studies with one derivative suggest that the functional group in the Hg(II) removal is the mercapto (SH) ligand. The dithioacetal group in (ClCOCH 2 S) 2 CHPh ( 2 ) was hydrolyzed during its reaction with amine (O) 3 Si(CH 2 ) 3 NH 2 ( 3 ) grafted on silica gel to give the mercapto ligand (O) 3 Si(CH 2 ) 3 NHCOCH 2 SH ( 4 ). The silica gel grafted with the mercapto ligand 4 selectively removed Hg 2+ ions with reported high capacities." @default.
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• W2013295008 date "2004-05-01" @default.
• W2013295008 modified "2023-09-23" @default.
• W2013295008 title "Mechanistic investigation of hydrolysis reactions of dithioacetal derivatives grafted on silica gels" @default.
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• W2013295008 doi "https://doi.org/10.1016/j.talanta.2003.10.026" @default.
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