Matches in SemOpenAlex for { <https://semopenalex.org/work/W2013301596> ?p ?o ?g. }
- W2013301596 endingPage "1007" @default.
- W2013301596 startingPage "1003" @default.
- W2013301596 abstract "The partitioning of reaction exothermicity into relative translational energy of the products of gas-phase SN2 (F− + CH3Cl) and nucleophilic aromatic substitution (F− + C6H5Cl) reactions has been investigated using kinetic energy release Fourier transform ion cyclotron resonance spectroscopy. The chloride product ion is observed to be highly translationally excited for the SN2 reaction, indicating a cold internal energy distribution for the products. For the chlorobenzene reaction the products are not generated with large translational energies. The results are compared with a statistical model. Ion-intensity profiles for the CH3Cl reaction deviate significantly from the statistical model whereas the chlorobenzene results are consistent with this model. The kinetic energy release for the CH3C1 reaction is compared with energy-disposal results for the photodissociation and dissociative electron-attachment processes of halomethanes. In all three cases a node in the molecular orbital between the carbon atom and the departing halogen results in a repulsive energy release. Ion-retention curves for the nucleophilic aromatic substitution reaction are consistent with the existence of a long-lived ion-dipole complex on the exit channel for this reaction." @default.
- W2013301596 created "2016-06-24" @default.
- W2013301596 creator A5004061975 @default.
- W2013301596 creator A5059767664 @default.
- W2013301596 creator A5083130490 @default.
- W2013301596 date "1991-11-01" @default.
- W2013301596 modified "2023-10-18" @default.
- W2013301596 title "Energy disposal in gas-phase nucleophilic displacement reactions" @default.
- W2013301596 cites W1967097295 @default.
- W2013301596 cites W1967441190 @default.
- W2013301596 cites W1968521179 @default.
- W2013301596 cites W1976373157 @default.
- W2013301596 cites W1978496693 @default.
- W2013301596 cites W1979504327 @default.
- W2013301596 cites W1981472331 @default.
- W2013301596 cites W1981810026 @default.
- W2013301596 cites W1982374391 @default.
- W2013301596 cites W1986159404 @default.
- W2013301596 cites W1997649792 @default.
- W2013301596 cites W2002711716 @default.
- W2013301596 cites W2006758337 @default.
- W2013301596 cites W2007354021 @default.
- W2013301596 cites W2009255888 @default.
- W2013301596 cites W2012232446 @default.
- W2013301596 cites W2020404327 @default.
- W2013301596 cites W2021014212 @default.
- W2013301596 cites W2022155038 @default.
- W2013301596 cites W2026537595 @default.
- W2013301596 cites W2030287744 @default.
- W2013301596 cites W2030893366 @default.
- W2013301596 cites W2037086632 @default.
- W2013301596 cites W2037904553 @default.
- W2013301596 cites W2044335570 @default.
- W2013301596 cites W2054406265 @default.
- W2013301596 cites W2063443172 @default.
- W2013301596 cites W2065071311 @default.
- W2013301596 cites W2066236602 @default.
- W2013301596 cites W2068221395 @default.
- W2013301596 cites W2086309698 @default.
- W2013301596 cites W2087664198 @default.
- W2013301596 cites W2089336107 @default.
- W2013301596 cites W2316700575 @default.
- W2013301596 cites W2336288085 @default.
- W2013301596 cites W255112979 @default.
- W2013301596 cites W2568273105 @default.
- W2013301596 cites W2950386231 @default.
- W2013301596 cites W2951648924 @default.
- W2013301596 cites W2952421090 @default.
- W2013301596 cites W2952811116 @default.
- W2013301596 cites W3004493114 @default.
- W2013301596 cites W3004948211 @default.
- W2013301596 cites W4233262796 @default.
- W2013301596 cites W4239584850 @default.
- W2013301596 cites W4256274639 @default.
- W2013301596 doi "https://doi.org/10.1002/oms.1210261118" @default.
- W2013301596 hasPublicationYear "1991" @default.
- W2013301596 type Work @default.
- W2013301596 sameAs 2013301596 @default.
- W2013301596 citedByCount "34" @default.
- W2013301596 countsByYear W20133015962012 @default.
- W2013301596 countsByYear W20133015962013 @default.
- W2013301596 countsByYear W20133015962015 @default.
- W2013301596 countsByYear W20133015962016 @default.
- W2013301596 countsByYear W20133015962019 @default.
- W2013301596 crossrefType "journal-article" @default.
- W2013301596 hasAuthorship W2013301596A5004061975 @default.
- W2013301596 hasAuthorship W2013301596A5059767664 @default.
- W2013301596 hasAuthorship W2013301596A5083130490 @default.
- W2013301596 hasConcept C121332964 @default.
- W2013301596 hasConcept C135731615 @default.
- W2013301596 hasConcept C135889238 @default.
- W2013301596 hasConcept C145148216 @default.
- W2013301596 hasConcept C147789679 @default.
- W2013301596 hasConcept C161790260 @default.
- W2013301596 hasConcept C170552419 @default.
- W2013301596 hasConcept C178790620 @default.
- W2013301596 hasConcept C178907741 @default.
- W2013301596 hasConcept C181500209 @default.
- W2013301596 hasConcept C184779094 @default.
- W2013301596 hasConcept C185592680 @default.
- W2013301596 hasConcept C2776041390 @default.
- W2013301596 hasConcept C54582936 @default.
- W2013301596 hasConcept C62520636 @default.
- W2013301596 hasConcept C75473681 @default.
- W2013301596 hasConcept C9061509 @default.
- W2013301596 hasConcept C96765332 @default.
- W2013301596 hasConceptScore W2013301596C121332964 @default.
- W2013301596 hasConceptScore W2013301596C135731615 @default.
- W2013301596 hasConceptScore W2013301596C135889238 @default.
- W2013301596 hasConceptScore W2013301596C145148216 @default.
- W2013301596 hasConceptScore W2013301596C147789679 @default.
- W2013301596 hasConceptScore W2013301596C161790260 @default.
- W2013301596 hasConceptScore W2013301596C170552419 @default.
- W2013301596 hasConceptScore W2013301596C178790620 @default.
- W2013301596 hasConceptScore W2013301596C178907741 @default.
- W2013301596 hasConceptScore W2013301596C181500209 @default.
- W2013301596 hasConceptScore W2013301596C184779094 @default.
- W2013301596 hasConceptScore W2013301596C185592680 @default.