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• W2013306776 abstract "Novel polyketides, citreoviripyrone A (1) and B (2), known citreomontanin (3), and (−)-citreoviridin (4) were isolated from the mycelium of the endophytic fungus. The endophytic fungus, which belongs to the genus Penicillium, was separated from surface-sterilized healthy leaves of Catharanthus roseus. The structures of 1 and 2 were determined on the basis of NMR data, and 1 was characterized as an α-pyrone polyketide featuring bicyclo[4.2.0]octadiene. The biomimetic synthesis of 1 and 2 from 3 elucidated a plausible biosynthetic pathway. Both Zn(II)-type and NAD+-dependent histone deacetylase inhibitors significantly enhanced the production of 1 and 3." @default.
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• W2013306776 date "2013-02-13" @default.
• W2013306776 modified "2023-09-25" @default.
• W2013306776 title "Structures and Biomimetic Synthesis of Novel α-Pyrone Polyketides of an Endophytic <i>Penicillium</i> sp. in <i>Catharanthus roseus</i>" @default.
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• W2013306776 doi "https://doi.org/10.1021/ol303506t" @default.
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