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- W2013313180 abstract "PhosphateZrO 2 Si 2 O catalysts were synthesized by sol-gel method using tributyl phosphite, zirconium propoxide, and tetraethyl orthosilicate as precursors. They were characterized by N 2 adsorption, 31 P CP MAS NMR, and DRIFTS. At lower P content, monomeric phosphates were formed on the surface of the catalysts, which were mainly responsible for the isopropanol dehydration activity. At higher P content, polyphosphates were formed, and thus, the dehydration activity decreased. An optimum P content for dehydration activity was found to be at 10 mol%.Key words: sol-gel synthesis, ternary oxides, phosphate, acid catalyst, alcohol dehydration, 31 P CP MAS NMR, N 2 adsorption, DRIFTS." @default.
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- W2013313180 date "2001-08-01" @default.
- W2013313180 modified "2023-09-27" @default.
- W2013313180 title "Sol-gel synthesis of ternary phosphate-ZrO<sub>2</sub>-SiO<sub>2</sub> catalysts for alcohol dehydration" @default.
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- W2013313180 doi "https://doi.org/10.1139/v01-108" @default.
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