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- W2013320199 abstract "Effect of electroactive ferrocene on the optical and electrochemical properties ofpolythiophenes were examined. Thus the ferrocene unit were introduced into polythiophenesby Grignard metathesis (GRIM) method to produce ferrocene substituted polythiophenes(PThFc). These polymers were characterized by GPC, NMR, UV-Vis absorption spectrum,and cyclic voltammogram (CV). The PThFc showed lower redox potential and reversibleelectrochemical redox state due to the ferrocenyl functional group, as determined by the CV.The absorption maxima of PThFc was 556 nm in the film state with a broad absorption bandcovering from 350 nm to 650 nm. Fluorescence quenching efficiency of PL for the PThFccontaining films was determined as > 90%. The short-circuit current densities (Jsc) for thecell containing PThFc was highly dependent on the thermal annealing process, indicating thatthe photovoltaic properties could be optimized by the control of polymer structure. (PThFc)." @default.
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- W2013320199 date "2011-02-10" @default.
- W2013320199 modified "2023-09-23" @default.
- W2013320199 title "Synthesis and characterization of thiophene-based conjugated copolymer containing ferroceneunits for organic electronics" @default.
- W2013320199 doi "https://doi.org/10.1117/12.874668" @default.
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