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- W2013321860 abstract "A mild method for the preparation of S-aryl thioacetates by hetero cross-coupling reactions of aryl bromides or aryl triflates with potassium thioacetate is described. The reaction proceeded smoothly in toluene at 110 °C, mediated by catalytic Pd2(dba)3 in combination with CyPF-tBu as the ligand. Neither the presence of a base nor microwave conditions were required. The formed S-aryl thioacetate proved to be stable under flash chromatographic conditions and could be rapidly converted into the corresponding thiol under mildly basic conditions." @default.
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- W2013321860 date "2010-12-01" @default.
- W2013321860 modified "2023-10-11" @default.
- W2013321860 title "A simple, base-free preparation of S-aryl thioacetates as surrogates for aryl thiols" @default.
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- W2013321860 doi "https://doi.org/10.1016/j.tetlet.2010.10.125" @default.
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