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- W2013336738 abstract "A new 1,3,4-oxadiazole-containing bispyridyl ligand, namely 5-(pyridin-4-yl)-3-[2-(pyridin-4-yl)ethyl]-1,3,4-oxadiazole-2(3 H )-thione ( L ), has been used to create the novel complexes tetranitratobis{μ-5-(pyridin-4-yl)-3-[2-(pyridin-4-yl)ethyl]-1,3,4-oxadiazole-2(3 H )-thione}zinc(II), [Zn 2 (NO 3 ) 4 (C 14 H 12 N 4 OS) 2 ], (I), and catena -poly[[[dinitratocopper(II)]-bis{μ-5-(pyridin-4-yl)-3-[2-(pyridin-4-yl)ethyl]-1,3,4-oxadiazole-2(3 H )-thione}] nitrate acetonitrile sesquisolvate dichloromethane sesquisolvate], {[Cu(NO 3 )(C 14 H 12 N 4 OS) 2 ]NO 3 ·1.5CH 3 CN·1.5CH 2 Cl 2 } n , (II). Compound (I) presents a distorted rectangular centrosymmetric Zn 2 L 2 ring (dimensions 9.56 × 7.06 Å), where each Zn II centre lies in a {ZnN 2 O 4 } coordination environment. These binuclear zinc metallocycles are linked into a two-dimensional network through nonclassical C—H...O hydrogen bonds. The resulting sheets lie parallel to the ac plane. Compound (II), which crystallizes as a nonmerohedral twin, is a coordination polymer with double chains of Cu II centres linked by bridging L ligands, propagating parallel to the crystallographic a axis. The Cu II centres adopt a distorted square-pyramidal CuN 4 O coordination environment with apical O atoms. The chains in (II) are interlinked via two kinds of π–π stacking interactions along [0overline 11]. In addition, the structure of (II) contains channels parallel to the crystallographic a direction. The guest components in these channels consist of dichloromethane and acetonitrile solvent molecules and uncoordinated nitrate anions." @default.
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- W2013336738 date "2013-06-13" @default.
- W2013336738 modified "2023-09-25" @default.
- W2013336738 title "Zn<sup>II</sup>and Cu<sup>II</sup>complexes generated from 5-(pyridin-4-yl)-3-[2-(pyridin-4-yl)ethyl]-1,3,4-oxadiazole-2(3<i>H</i>)-thione" @default.
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- W2013336738 doi "https://doi.org/10.1107/s0108270113012134" @default.
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